MVC is part of the asp.net framework. It is a programming model which helps you create an asp.net web application, but MVC is much slicker and cleaner then asp.net Webforms environment.

This video presents how developers can build RESTful solutions using Microsoft’s technologies, especially with WCF and .NET.
http://www.infoq.com/presentations/Building-Systems-with-REST

This short video discusses the benefits and drawbacks of using the MVC Model-View-Controller approach versus the web forms. Model–view–controller (MVC) is an architectural pattern used in software development. The pattern isolates “domain logic” (the application logic for the user) from the user interface (input and presentation), permitting independent development, testing and maintenance of each (separation of concerns).

This video explains how to build a RESTful .NET application with OpenRasta 3. OpenRasta is a resource-oriented open source development framework targeting the Microsoft .NET platform for building web-based applications and services. It focuses around resources and HTTP methods to simplify the creation of ReST-friendly interfaces.
http://www.infoq.com/presentations/Building-a-RESTful-Architecture-with-OpenRasta

This video explains Reactive Extensions (Rx), a library for composing computations over asynchronous event streams of data for .NET and Javascript, the concepts and implementation of Rx and more.
http://www.infoq.com/interviews/de-smet-rx